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| CO2在原油中的扩散规律及变扩散系数计算方法 |
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赵仁保1,敖文君2,肖爱国1,严伟1,于志海1,3,夏晓婷1
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(1.中国石油大学油气资源与探测国家重点实验室,北京 102249;2.中海油能源发展股份有限公司工程技术分公司,天津 300452;3.中国石油集团渤海钻探工程有限公司,天津 300457)
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| 摘要: |
| 通过室内实验与理论计算相结合建立CO2在体相及多孔介质中变扩散系数的计算模型,得到不同黏度原油在多孔介质中的变扩散系数,并结合文献中的常扩散系数计算模型,利用MATLAB进行数据拟合与编程,对比分析两种计算方法下的平均扩散系数以及CO2在溶液中的传质扩散行为。结果表明:原油黏度越大,扩散系数越小,扩散平衡时间越长;采用变扩散系数可以更好地解释扩散过程中的非稳定阶段与稳定阶段,其扩散行为更符合实际条件下的扩散规律。 |
| 关键词: 扩散系数 CO2 Fick定律 传质 |
| DOI：10.3969/j.issn.1673-5005.2016.03.018 |
| 分类号::TE 357.11 |
| 基金项目:国家重点基础研究发展计划(2015CB250904); 国家自然科学基金项目(51274217) |
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| Diffusion law and measurement of variable diffusion coefficient of CO2 in oil |
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ZHAO Renbao1, AO Wenjun2, XIAO Aiguo1, YAN Wei1, YU Zhihai1,3, XIA Xiaoting1
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(1.State Key Laboratory of Petroleum Resource ＆ Prospecting, China University of Petroleum, Beijing 102249, China;2.Engineering Technology Company of CNOOC Energy Technology ＆ Services Limited, Tianjin 3000452, China;3.CNPC Bohai Drilling Engineering Company Limited, Tianjin 3000457, China)
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| Abstract: |
| A mathematical model of variable diffusion coefficient of CO2 which can be used in bulk and porous media was established through the experiment and theoretical calculation. The variable diffusion coefficients of CO2 in oils with different viscosity were calculated with this developed model. In order to validate this model, a traditional model of constant diffusion coefficient was used to calculate the average diffusion coefficient. The calculations with MATLAB software for the two models to analyze the diffusion coefficients and diffusion behaviors were also compared. The results show that the greater the viscosity of crude oil, the smaller the diffusion coefficient and the longer the diffusion equilibrium time. Diffusion behaviors of real condition, which contains unstable and stable stages, can be explained by the variable diffusion coefficient model with better results. |
| Key words: diffusion coefficient CO2 Fick law mass-transfer |
