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Distribution, composition and structure of naphthenic acid in Bohai crude oil
ZHANG Zhen1,2, HU Fang fang3, ZHANG Yu zhen1
(1.State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Dongying 257061, China;2.China Petroleum & Chemical Corporation, Beijing 100728, China;3.Testing Center of Shengli Oilfield of SINOPEC, Dongying 257000, China)
Abstract:
The naphthenic acid in Bohai PL 19 3 crude was separated and purified firstly. Then, the composition, structure, as well as the distribution of naphthenic acids were analyzed and characterized by elemental analysis, IR and GC MS. The results indicate that naphthenic acid not only consists in the diesel oil fraction, but also in vacuum gas oil at high percentage. The main components of naphthenic acids are mono , di and tri cyclic ones, with few aromatic ring ones. And in heavier distillations, the structures get more complicated.
Key words:  crude oil  the Bohai Sea  naphthenic acid  composition  structure