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Oxidizing pyrolysis of Huadian oil shale and its product distribution |
SUN Youhong1,2,3,4, XU Shaotao1,2, YANG Qinchuan1,2, LAI Cheng1, GUO Mingyi1,3
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(1.College of Construction Engineering, Jilin University, Changchun 130026, China;2.National-Local Joint Engineering Laboratory of In-situ Conversion, Drilling and Exploitation Technology for Oil Shale, Jilin University, Changchun 130026, China;3.Key Laboratory of Ministry of Natural Resources for Drilling and Exploitation Technology in Complex Conditions, Jilin University, Changchun 130026, China;4.School of Engineering and Technology, China University of Geosciences(Beijing), Beijing 100083, China)
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Abstract: |
The influences of atmosphere and temperature on solid residue, shale oil and gas, as well as yields of shale oil and compositions of shale oil and gas were investigated by XRD, TG, FT-IR, elemental analysis, four components analysis and GC-MS. The results show that the pyrolysis of oil shale can occur at a lower external temperature in oxidative atmosphere. Shale oil yield can reach 51% of Fisher assay oil content at 350 ℃ in air, which is 3.5 times higher than that in nitrogen. And the quality of shale oil is improved. It is also found that atmosphere and temperature are the key factors affecting oil shale pyrolysis, and oxidative atmosphere has a great potential in the development and utilization of oil shale. |
Key words: oil shale pyrolysis parameter oxidizing pyrolysis product characterization |
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